Mesoporous Ni–CeO2 Catalyst with Enhanced Selectivity and Stability for Reverse Water–Gas Shift Reaction

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Luhui Wang¹  Cunyu Zhao³  Hui Liu² 

[1] Department of Chemical Engineering, School of Petrochemical and Energy Engineering, Zhejiang Ocean University;Chemical Laboratory, School of Food and Pharmaceutical, Zhejiang Ocean University;Mechanical Engineering Department, University of Wisconsin-Milwaukee

关键词: Reverse Water–Gas Shift Reaction;    Ni–CeO2;    Mesoporous Catalyst;    Selectivity;    Stability;   

DOI  :  10.1252/jcej.15we128

来源: Maruzen Company Ltd

【 摘 要 】

References(27)Mesoporous Ni–CeO2 catalyst was prepared by a polymer (P123)-assisted co-precipitation method and used for reverse water–gas shift reaction. Compared with the catalysts prepared by traditional co-precipitation methods, the mesoporous Ni–CeO2 catalyst shows higher stability for the reverse water–gas shift reaction at 600°C but with no formation of the side product CH4. Moreover the mesoporous Ni–CeO2 catalyst is also highly active for reverse water–gas shift reaction. TPR and XRD results suggest that, in the mesoporous Ni–CeO2 catalyst, Ni2+ ions are incorporated into the CeO2 lattice to form a NixCeyO2 solid solution, which produces a large number of oxygen vacancies and enhances the reducibility of the surface CeO2. The excellent performance of the mesoporous catalyst is related to the lack of exposed NiO particle on the surface, and the large amount of oxygen vacancies in the uniform mesoporous structure.

【 授权许可】

Unknown