JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | |
Chromium Addition to Alumina-Supported Platinum Catalysts and Effect on Catalytic Activity in Methane Combustion | |
Sakae Takenaka1  Hideki Matsune1  Mardwita1  Masahiro Kishida1  | |
[1] Department of Chemical Engineering, Graduate School of Engineering, Kyushu University | |
关键词: Methane Combustion; Impregnation Method; Platinum and Chromium Catalysts; Chromium Effect; X-Ray Photoelectron Spectroscopy; | |
DOI : 10.1252/jcej.12we025 | |
来源: Maruzen Company Ltd | |
【 摘 要 】
References(21)Cited-By(1)We investigated the addition of chromium to alumina-supported Pt catalysts and its effect on catalytic activity in methane combustion. The Pt and Cr binary alumina-supported catalysts exhibited much higher activity than those without Cr. Alumina-supported Cr catalysts contain two chromium species, Cr3+ and Cr6+. From XPS analysis, it was found that more Cr6+ species existed in the binary catalysts than in the single alumina-supported Cr catalysts. Pt species in the binary catalysts may promote Cr oxidation. Since Cr6+ species are known to be more active than Cr3+ species in oxidation reactions, the increase in Cr6+ in the binary catalysts may contribute to their higher activity compared with the Pt/Al2O3 catalyst.
【 授权许可】
Unknown
【 预 览 】
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RO201912080696842ZK.pdf | 19KB | download |