Removal of Chromate and Borate from Solution Using Calcination Products of Ca(OH)2– and CaCO3–Al(OH)3 Mixtures

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Yuki Hiraga¹  Naoya Shigemoto¹ 

[1] Chemical Technology Department, Shikoku Research Institute, Inc.

关键词: Removal;    Chromate;    Borate;    Calcination Product;   

DOI  :  10.1252/jcej.11we203

来源: Maruzen Company Ltd

【 摘 要 】

References(22)Cited-By(2)Ca(OH)2–Al(OH)3 and CaCO3–Al(OH)3 mixtures with Ca/(Ca+Al) ratios in the range 0 to 1 were calcined in the temperature range 873–1673 K for studying the effect of the calcination temperature and Ca/(Ca+Al) ratio on the calcination products. XRD analysis showed that the mixtures with Ca/(Ca+Al) ratios in the range 0.68–0.83 and calcined around 1273 K gave lime (CaO) as the major product and mayenite (Ca12Al14O33), Ca9Al6O18, and Ca5Al6O14 as the minor products. These calcination products indicated that the efficiencies of the removal of chromate and borate from the solution were high. Upon immersing these calcination products in chromate and borate solutions, Ca4Al2CrO10·12H2O and Ca4Al2(HBO3)0.5(OH)13·6H2O were formed, respectively; the Ca/(Ca+Al) molar ratio in these compounds was 0.68, which was close to that in the raw mixtures. A Ca/(Ca+Al) ratio in the range 0.68–0.83 resulted in the optimum removal of chromate and borate from the solution. The Ca/(Ca+Al) ratio was more effective than these crystalline components in these calcination products. Further, Ca(B(OH)4)2·2H2O precipitated as a result of borate removal.

【 授权许可】

Unknown