Subcritical Water Assisted Clean Cross-Aldol Reactions

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Kazuya Kobiro¹  Pengyu Wang¹ 

[1] School of Environmental Science and Engineering, Kochi University of Technology

关键词: Subcritical Water;    Clean Cross-Aldol Reaction;    Benzaldehyde/Acetone;    Acetophenone/1;    3;    5-Trioxane;    ZnCl2;   

DOI  :  10.1252/jcej.10we308

来源: Maruzen Company Ltd

【 摘 要 】

References(40)Cited-By(3)This study investigates the use of subcritical water in cross-aldol reactions containing both organic materials, benzaldehyde/acetone and acetophenone/1,3,5-trioxane, and an inorganic material, ZnCl2. The results are compared to those obtained under solvent-free conditions. It is found that water suppresses the loss of organic materials and accelerates the formation of cross-aldol reaction products. Satisfactory yields (46–63%) were obtained with ZnCl2.

【 授权许可】

Unknown