期刊论文详细信息
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Plate-Type Anodic Alumina Supported Ruthenium Catalysts for Steam Reforming of Kerosene: Influence of Calcination on Catalysts Reactivity
Yu Guo1  Jian Chen1  Lu Zhou1  Makoto Sakurai1  Huabo Li1  Hideo Kameyama1 
[1] Department of Chemical Engineering, Tokyo University of Agriculture and Technology
关键词: Kerosene;    Anodic Alumina Catalyst;    Ruthenium;    Steam Reforming;    Ethanol;   
DOI  :  10.1252/jcej.09we150
来源: Maruzen Company Ltd
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【 摘 要 】

References(20)Cited-By(3)Metal monolithic anodic alumina supported Ru catalysts prepared by impregnation method are employed to the steam reforming of kerosene. The characteristics of the resulting catalysts are analyzed by using ICP, BET, CO-Pulse and temperature-programmed reduction (TPR) measurements. The calcination on the catalyst reactivity is investigated. We found that calcination operation during the catalyst preparation is not an essential procedure; on the contrary, it decreases the catalyst dispersion, further resulting in poor activity. Furthermore, the anodic alumina supported Ru catalyst prepared without calcination at 500°C, provided better activity and stability than a commercial catalyst (S/C = 3.0, F/W = 80,000 mL/(h·g), 450–750°C). In particular, pre-reduction with hydrogen over catalyst is considered to not be an essential operation due to the excellent activity and stability in the reforming reaction.

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