Plasma Conversion of Methane and CO2 Using a Tubular Circle-to-Plate Reactor

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Eiji Suzuki³  Mamoru Okumoto¹  Tatsuaki Yashima¹  Jun Shimogami²  Shuiliang Yao¹  Kazuhiko Madokoro² 

[1] Chemical Research Group, Research Institute of Innovative Technology for the Earth;Department of Physics, Kyoto Sangyo University;Department of Fine Material Engineering, Shinshu University

关键词: Pulsed Plasma;    Methane;    Acetylene;    Energy Efficiency;    Reaction Engineering;   

DOI  :  10.1252/jcej.36.435

来源: Maruzen Company Ltd

【 摘 要 】

References(14)Cited-By(2)For reducing amount of CO2 emitted by acetylene production, a research on energy efficient plasma technologies for converting methane to acetylene was conducted, resulting in development of a tubular circle-to-plate (CTP) type of reactor. The CTP reactor driven by a pulsed plasma converted mixture of methane and CO2 to acetylene, ethylene, ethane, carbon monoxide, higher hydrocarbons such as C3 and C4, and hydrogen. CO2 was used mainly for stabilizing the plasma discharge, though it also reacted with methane yielding CO and hydrogen. A maximum energy efficiency of 4 mmol/kJ, which was obtained at a pulse frequency of 625 Hz, indicated a potential to reduce CO2 emission from the acetylene production. The energy efficiency decreased at a pulse frequency above 625 Hz with the CTP reactor, which differed from results with co-axial cylindrical (CAC) and point-to-point (PTP) type reactors. Acetylene selectivity was 62% at maximum at 8 kHz.The plasma technology would also be useful for relocating conventional fossil fuel dependent acetylene production to the sun-belt where solar thermal power, which is relatively inexpensive among renewable energies, can be utilized to generate plasma. Such relocation accompanied by replacement of fossil energy with renewable energy would result in reduction of global CO2 emission.

【 授权许可】

Unknown