Kinetic Study on 2-Methyl-1-Butanol Dehydration Catalysed by Ion Exchange Resin

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Shigeo Goto¹  Farid Aiouache¹ 

[1] Department of Chemical Engineering, Nagoya University

关键词: Chemical Reaction;    Kinetics;    Water Inhibition;    Ion Exchange Resin;    2-Methyl 1-Butene;    2-Methyl 2-Butene;   

DOI  :  10.1252/jcej.35.436

来源: Maruzen Company Ltd

【 摘 要 】

References(12)Cited-By(8)The dehydration of 2-methyl 1-butanol (2M1BOH) in the liquid phase was studied by using an ion-exchange resin, Amberlyst 15 in the H+ form. Experiments were carried out in a batch reactor with the dry resin as a catalyst. Considering the inhibition effect of water, the rate expressions based on the Langmuir-Hinshelwood model were formulated. The sorption equilibrium model between liquid and resin phases during resin swelling was included in kinetic modelling. The cross-linked ion-exchange resin was highly selective to water at the beginning of the reaction. The experimental results agreed well with the calculated ones.

【 授权许可】

Unknown