Solvent Extraction Equilibrium of Zinc(II) from Ammonium Chloride Medium by CYANEX 923 in Solvesso 100

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

SUSANA MARTÍNEZ¹  FRANCISCO JOSÉ ALGUACIL¹ 

[1] Centro Nacional de Investigaciones Metalúrgicas (CSIC), Ciudad Universitaria

关键词: Solvent Extraction;    Chemical Equilibrium;    Zinc;    CYANEX 923;    Ammonium Chloride;   

DOI  :  10.1252/jcej.34.1439

来源: Maruzen Company Ltd

【 摘 要 】

References(17)Cited-By(4)The extraction equilibrium of zinc in ammonium chloride medium with CYANEX 923 (phosphine oxides mixture) in Solvesso 100 has been investigated. The distribution coefficient of zinc was independent of the equilibrium pH; this independence being attributable to a solvation extraction mechanism. Slope analysis for the system using dilute zinc solution reveals that two moles of CYANEX 923 react with one mol of zinc. The stoichiometric factor of water in the extraction reaction is found to be 2, whereas experimental data indicated that two chloride ions are involved for each metal extracted. The extraction reaction is exothermic (ΔH° = −42.0 kJ mol-1).

【 授权许可】

Unknown