Hydrogenolysis of Methyl Oleate over Oxide Catalyst Derived from Hydrogen Storage Alloy

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Nobuyasu Chikamatsu¹  Tomohiko Tagawa¹  Shigeo Goto¹ 

[1] Department of Chemical Engineering, Nagoya University

关键词: Chemical Reaction;    Hydrogenolysis;    Methyl Oleate;    Kinetics;    Catalyst;    Unsaturated Alcohol;   

DOI  :  10.1252/jcej.24.604

来源: Maruzen Company Ltd

【 摘 要 】

References(17)Cited-By(2)A mixed oxide catalyst was prepared from a binary hydrogen storage alloy, Mg2Cu, and its activity and selectivity were compared with those of conventional CuCrO catalyst. The catalyst’s activity was stable for the synthesis of C18 alcohol by gas-phase hydrogenolysis of methyl oleate in a continuous-flow reactor at 553 K under atmospheric pressure. Considerable amounts of unsaturated alcohol were produced together with saturated alcohol. From a kinetic study the rate equation was formulated for each alcohol. From XRD analysis, active sites are thought to be copper species on MgO support.

【 授权许可】

Unknown