Recovery and Purification of Boron from Coal Fly Ash

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

Eiichi Kunugita¹  Isao Komasawa¹  Izumi Tsuboi¹ 

[1] Department of Chemical Engineering, Osaka University

关键词: Ion Exchange;    Rare Metal;    Selective Adsorption;    Coal Fly Ash;    Acid Leaching;    Boron;    Metal Recovery Process;    Solvent Extraction;   

DOI  :  10.1252/jcej.23.480

来源: Maruzen Company Ltd

【 摘 要 】

References(17)Cited-By(16)A process has been developed to recover boron from coal fly ash in which boron exists at low concentration in a mixture of high concentration of less desirable species. Of the boron contained in the ash, 72% can be leached with dilute sulfuric acid when the pH of the final pregnant liquor is kept at 7.0, the other undesirable transition metals being left in the residue. The boron is then concentrated using chelating resin with a functional group of glucamic type. Eighty-seven percent of the boron is recovered and is then concentrated to 3.6 g/dm3 with a purity of 98.9 percent. This liquor is further treated to remove impurities by a solvent extraction technique, employing 2-ethyl-1,3-hexanediol as an extractant, and a purified liquor for borax production is obtained.

【 授权许可】

Unknown