JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | |
A MEMBRANE REACTOR USING MICROPOROUS GLASS FOR SHIFTING EQUILIBRIUM OF CYCLOHEXANE DEHYDROGENATION | |
KENJI HARAYA1  NAOTSUGU ITOH1  TOSHIKATSU HAKUTA1  YUJI SHINDO1  | |
[1] National Chemical Laboratory for Industry | |
关键词: Membrane Reactor; Microporous Glass Membrane; Reversible Reaction; Equilibrium Shift; Dehydrogenation of Cyclohexane; | |
DOI : 10.1252/jcej.21.399 | |
来源: Maruzen Company Ltd | |
【 摘 要 】
References(10)Cited-By(45)A membrane reactor, which is a double-tubular reactor equipped with a selective membrane tube as the inner tube, was proposed. Such a reactor makes it possible to obtain a product yield of a reversible reaction beyond its equilibrium value by continuous removal of the products during reaction. A microporous glass tube was employed as the selective membrane, through which gases permeate almost according to Knudsen''s law. Experiments in the dehydrogenation of cyclohexane to benzene as a model reaction were carried out, using the membrane reactor under atmospheric pressure in the range of 453-493 K. It was shown experimentally and theoretically that a marked increase in conversion over that at equilibrium can be achieved.
【 授权许可】
Unknown
【 预 览 】
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