EXTRACTION EQUILIBRIUM OF Ce(III), Pr(III) AND Nd(III) WITH ACIDIC ORGANOPHOSPHORUS EXTRACTANTS

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

WATARU EGUCHI¹  HARUHIKO ONO¹  HITOSHI OHYA¹  YASUSHIGE MORI¹ 

[1] Department of Chemical Engineering, Kyoto University

关键词: Extraction Equilibrium;    Rare Earth;    Acidic Organophosphorus Extractants;    EHPNA;    Additional Complex;   

DOI  :  10.1252/jcej.21.86

来源: Maruzen Company Ltd

【 摘 要 】

References(5)Cited-By(27)Solvent extraction has recently attracted major interest for industrial-scale separation of lanthanoids, alike ion exchange. It is well known that di(2-ethylhexyl)phosphoric acid (henceforth D2EHPA) is an effective extractant for the mutual separation of lanthanoids, because of its high separation factor. 2-Ethylhexylphosphonic acid mono2-ethylhexyl ester (henceforth EHPNA), which is similar in its chemical structure as D2EHPA, has a higher ability of back extraction at low acid concentration than D2EHPA. In this paper, the extraction equilibrium of cerium, praseodymium and neodymium by EHPNA was investigated and was compared with that by D2EHPA. It was found that the existence of two kinds of complexes should be considered in the region of high concentration of EHPNA, unlike the case of D2EHPA. The extraction of metals from the solution of mixed lanthanoids can be explained based on the extraction mechanism of individual elements.

【 授权许可】

Unknown