JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | |
KINETICS OF M ETHAN ATI ON OF CARBON MONOXIDE AND CARBON DIOXIDE | |
HAKUAI INOUE1  MASAKI FUNAKOSHI1  | |
[1] Department of Chemical Engineering, University of Tokyo | |
关键词: Chemical Reaction; Chemical Reactor; Methanation; Carbon Monoxide; Carbon Dioxide; Reaction Kinetics; Reaction Mechanism; | |
DOI : 10.1252/jcej.17.602 | |
来源: Maruzen Company Ltd | |
【 摘 要 】
References(12)Cited-By(8)The kinetics of reaction of carbon monoxide and carbon dioxide with hydrogen in a nickel catalyst tube wall reactor were investigated experimentally and the reaction mechanisms were clarified. The observed rate laws were -rco = (k1PH2P1/2CO)/(1 + KCOPCO) for carbon monoxide, and -rco2 = (k''PH2P1/3CO2)/(1 + KCO2PCO2 + KH2 + KH2OPH2O)for carbon dioxide at low partial pressure. These reaction rate laws were derived theoretically from the proposed reaction mechanism. For a mixture of carbon monoxide and carbon dioxide the kinetics of the reaction proved to be well accounted for by the same reaction mechanism.
【 授权许可】
Unknown
【 预 览 】
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