A NEW SIMULATION PROCEDURE FOR MULTISTAGE WATER/HYDROGEN EXCHANGE COLUMN FOR HEAVY WATER ENRICHMENT

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

MASAHIRO KINOSHITA¹  IORI HASHIMOTO¹  TAKEICHIRO TAKAMATSU¹ 

[1] Japan Atomic Energy Research Institute

关键词: Isotopic Exchange;    Exchange Column;    Simulation;    Water;    Hydrogen;    Deuterium;    Multistage Column;    Heavy Water Enrichment;    Newton Raphson Method;    Distillation Column;   

DOI  :  10.1252/jcej.17.255

来源: Maruzen Company Ltd

【 摘 要 】

References(12)Cited-By(6)A powerful new simulation procedure is developed for the multistage water/hydrogen exchange column for heavy water enrichment. In comparison with the distillation column, the exchange column considered here has several specific features such as the presence of three streams (liquid water, water vapor and hydrogen gas), occurrence of isotopic exchange reactions and much more complex column configuration comprising two different kinds of stages, a catalytic oxidizer at the top and an electrolytic cell at the bottom. The main calculational loop proposed here is the Newton-Raphson method where the number of independent variables is just equal to the total number of water/vapor scrubbing stages. Unlike the previously reported procedures for the exchange column, the present procedure is applicable even in cases where the deuterium concentration is significantly high, varying greatly from stage to stage within the column.

【 授权许可】

Unknown