THE MICROSTRUCTURE AND PROPERTIES OF STARCH-POLYVINYL ALCOHOL-ALGINATE FILMS WITH COPAIBA AND LEMONGRASS OILS

Química Nova

Universidade Tecnológica Federal do Paraná, Dois Vizinhos, BR¹  Alfaro, Alexandre¹  Universidade Tecnológica Federal do Paraná, Francisco Beltrão, BR¹  Brandelero, Renata P. H.¹  Almeida, Fábio M. de¹ 

关键词:  ternary blends;    active packaging;    essential oils;    characterization;   

DOI  :  10.5935/0100-4042.20150098

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

Films obtained by blends between starch and other polymers and films developed with the addition of an oil can show higher water vapor barriers and improved mechanical properties. Films with starch/PVOH/alginate were obtained by adding copaiba and lemongrass essential oils (EOs). Films without oil served as the control. The microstructure, water vapor permeability (PVA), mechanical properties, and antifungal activity were determined for the films. The effects of the addition of the EOs on the properties of the films were dependent of the concentration and type of oil. The films with 0.5% lemongrass EO were similar to the control films. These films showed a 2.02 × 10-12 g s-1Pa m-1 PVA, 11.43 MPa tensile stress, 13.23% elongation, and 247.95 MPa/mm resistance at perforation. The addition of 1% of copaiba EO increased the PVA from 0.5 × 10-12 to 12.1 × 10-12 g s-1 Pa m-1 and the diffusion coefficient from 0.17 × 10-8 to 7.15 × 10-8m2/day. Films with quantities of EOs displayed fissures and micropores; the control films developed micropores with smaller diameters than films with EOs. The addition of EOs did not change the resulting infrared spectrum of the films. The films with oil displayed a diminished development of the Fusarium sp. culture, and the film without EOs did not display notable differences in the development of the culture. The starch/PVOH/alginate films with 0.5% lemongrass EO were the most suited for the development of a packaging active system.

【 授权许可】

Unknown