Co preferential oxidation on CuO/CeO2-TiO2 system

Química Nova

Maciel, Cristhiane Guimarães¹  Assaf, José Mansur¹  Universidade Federal de São Carlos, São Carlos, Brasil¹ 

关键词: PROX-CO;    copper;    ceria.;   

DOI  :  10.1590/S0100-40422010000900017

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

Cu catalysts supported on CeO2, TiO2 and CeO2/TiO2 were prepared by precipitation method and used for preferential oxidation of carbon monoxide contained in a hydrogen flow generated by methane steam reforming. The samples were characterized by XRD, BET and TPR techniques. The catalytic properties were studied in the 50-330ºC range by using a quartz micro-reactor vertically positioned on an electrical furnace. The results showed that the small copper particles generated with the lower metal content are the most easily reducible and give the best catalytic performance. In respect of support effect, the strong metal-support interaction and the redox characteristics of the CuOx-CeO2 series resulted in the best catalytic results, especially with the sample with 1% copper content.

【 授权许可】

Unknown