Development of a flotation method for preconcentration-separation of trace amounts of some metal ions in plant tissues prior to their FAAS determinations

Química Nova

University of Yasouj, Iran¹  Soylak, M.¹  Montazerozohori, M.¹  Marahel, F.¹  Omidiyeh Azad University, Omidiyeh, Iran¹  Ghaedi, M.¹  Shokrollahi, A.¹  University of Erciyes, Kayseri, Turkey¹ 

关键词: bis(2-hydroxyacetophenone)-1;    4-butanediimine;    metal;    flotation.;   

DOI  :  10.1590/S0100-40422010000200031

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

An efficient flotation method based on the combination of flame atomic absorption spectrometry (FAAS) and separation and preconcentration step for determination of Cr3+, Cu 2+, Co2+, Ni2+, Zn2+, Cd 2+, Fe3+ and Pb2+ ions in various real samples by the possibility of applying bis(2-hydroxyacetophenone)-1,4-butanediimine (BHABDI) as a new collector was studied. The influence of pH, amount of BHABDI as collector, sample matrix, type and amount of eluting agent, type and amount of surfactant as floating agent, ionic strength and air flow rates i.e. variables affecting the efficiency of the extraction system was evaluated. It is ascertained that metal ions such as iron can be separated simultaneously from matrix in the presence of 0.012 mM ligand, 0.025% (w/v) of CTAB to a test sample of 750 mL at pH 6.5. These ions can be eluted quantitatively with 6 mL of 1.0 mol L-1 HNO3 in methanol which lead to the enrichment factor of 125. The detection limits for analyte ions were in the range of 1.3-2.4 ng mL-1. The method has been successfully applied for determination of trace amounts of ions in various real samples.

【 授权许可】

Unknown