Ultrasound potentialities on the determination of the pesticide carbaryl using diamond electrodes

Química Nova

Avaca, Luis A.¹  Universidade de São Paulo, São Carlos, Brasil¹  Universidade Tiradentes, Aracaju, Brasil¹  Garbellini, Gustavo S.¹  Salazar-Banda, Giancarlo R.¹ 

关键词: boron-doped diamond;    sonoelectroanalysis;    food samples.;   

DOI  :  10.1590/S0100-40422010001000039

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

The potentiality of the use of ultrasound radiation in association with a boron-doped diamond electrode was evaluated on the voltammetric determination of the pesticide carbaryl. Improvements in the sensitivity, limit of detection and reproducibility of the measurements were observed due to both, the enhancement of mass transport and the cleaning of the electrode surface provided by ultrasound. Satisfactory recovery levels for carbaryl in pure water (96-98%) and pineapple juice (89-92%) for quiescent and sonovoltammetric methodologies were obtained. These methodologies can be alternative tools for the analyses of pesticides in fruit samples, mainly the insonated condition that improve the analytical performance and dispense intermediary cleanings of the electrode surface.

【 授权许可】

Unknown