Perovskite-type oxides to no reduction with CO

Química Nova

Assaf, Elisabete M.¹  Universidade de São Paulo, São Carlos, Brasil¹  Tanabe, Eurico Y.¹ 

关键词: perovskite;    lanthanum;    NO reduction with CO.;   

DOI  :  10.1590/S0100-40422009000500009

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

In this work, the perovskite-type oxides LaNiO3, LaMnO3, La0,7Sr0,3NiO3 and La0,7Sr0,3MnO3 were prepared by co-precipitation and tested in the NO reduction with CO at 400 and 500 ºC for 10 h. The catalysts were characterized by X-ray diffraction, temperature programmed reduction with hydrogen, nitrogen adsorption and chemical analysis. The nonstoichiometric oxygen was quantified by temperature programmed reduction, and the catalytic tests showed that the La0,7Sr0,3MnO3 catalyst presented the higher performance for the reduction reaction of NO with CO. The partial substitution of lanthanum by strontium increased the NO conversion and the N2 yield.

【 授权许可】

Unknown