Camphor: a good model for illustrating NMR techniques

Química Nova

Azeredo, Rodrigo Bagueira de V.¹  Universidade Federal Fluminense, Niterói, Brasil¹  Yoneda, Julliane Diniz¹  Leal, Kátia Zaccur¹  Universidade Federal do Rio de Janeiro, Rio de Janeirp, Brasil¹  Universität Potsdam, Potsdam, Germany¹  Kleinpeter, Erich¹  Seidl, Peter Rudolf¹ 

关键词: organic chemistry;    NMR spectroscopy;    camphor.;   

DOI  :  10.1590/S0100-40422007000800043

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

The use of Nuclear Magnetic Resonance spectroscopy to establish the three-dimensional structures of molecules is an important component of modern Chemistry courses. The combination of techniques that can be used for this purpose is conveniently illustrated by their application to the camphor molecule. This paper presents applications of several techniques used in NMR spectral interpretation in an increasing order of complexity. The result of individual experiments is illustrated in order to familiarize the user with the way connectivity through bonds and through space is established from 1D/2D-NMR spectra and molecular stereochemistry is determined from different NMR experiments.

【 授权许可】

Unknown