Comparison of Gold CD-R Types as Electrochemical Device and as Platform for Biosensors

Journal of the Brazilian Chemical Society

Ferreira, Antonio A. P.¹  Santos, Glauco P. dos¹  Mascini, Marcello¹  Universidade Estadual Paulista Júlio de Mesquita Filho , Araraquara, Brazil¹  Masaryk University, Brno, Czech Republic¹  Yamanaka, Hideko¹  University of Teramo, Teramo, Italy¹  Foguel, Marcos V.¹  Benedetti, Assis V.¹  Magnani, Marina¹  Skladal, Petr¹ 

关键词:  gold;    recordable compact discs;    biosensors;    surface characterization;    CDtrode;   

DOI  :  10.5935/0103-5053.20150308

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

The construction of gold electrodes using 3 kinds of gold recordable compact discs (CDtrodes) and characterization by electrochemical and spectroscopic techniques are herein reported. Following a surface pretreatment in 0.5 mol L-1 sulfuric acid (H2SO4), the electrochemical experiments were performed in the presence of redox couple ferro/ferricyanide [Fe(CN)6]3-/4-. The immobilization of an oligopeptide bio-inspired by acetylcholinesterase onto the CDtrode was also evaluated. Surface characterization was done by cyclic voltammetry, electrochemical impedance spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy and atomic force microscopy. CDtrodes are known to be of low cost, fast and simple construction. They are suitable for immobilizing biological molecules and could be used as disposable transducer for the construction of biosensors.

【 授权许可】

Unknown