Integrated Synthesis of Zeolites Using Coal Fly Ash: Element Distribution in the Products, Washing Waters and Effluent

Journal of the Brazilian Chemical Society

Pires, Marçal¹  Paprocki, Alexandre¹  Pontifícia Universidade Católica do Rio Grande do Sul, Porto Alegre, Brazil¹  Cardoso, Ariela M.¹  Ferrarini, Suzana F.¹ 

关键词:  zeolite;    coal fly ash;    toxic element;    element distribution;   

DOI  :  10.5935/0103-5053.20160093

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

Coal fly ash has been proposed as an alternative raw material for zeolite synthesis, however, the mobilization of toxic elements of this material into zeolite products, washing water and effluent is rarely addressed. In this study, Brazilian coal fly ash was used in the integrated synthesis (two steps) of zeolites Na-P1 and 4A and the distribution of approximately 40 major, minor and trace elements was investigated in all the input and output flows involved in the process. The mobilization of several elements was observed in the zeolite products, a number of which are highly toxic, such as As, Cd, Cr, Ni and Pb. With regard to the amount present in the ash, both zeolites were enriched in several elements, such as Ni in zeolite Na-P1 and As in zeolite 4A. The latter exhibited high purity, with most of the elements investigated having concentrations close to those measured in commercial zeolite 4A. Important information was gathered regarding zeolite synthesis using fly ash, which will ensure safer application of these materials and, if necessary, propose a contaminant-free synthesis route.

【 授权许可】

Unknown