Structural study and fluorescent property of a novel organic microporous crystalline material

Journal of the Brazilian Chemical Society

Zhang, Binglin¹  Yang, Meipan¹  Northwest University, Xi'an, China¹  Yang, Bingqin¹  Cheng, Zhao¹ 

关键词: X-ray diffraction;    hydrogen bond;    microporosity;    fluorescence;    luminescence lifetime;   

DOI  :  10.5935/0103-5053.20130276

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

A novel microporous organic material [(2-{2-[2-(bis-methoxycarbonylmethylamino)phenoxy]ethoxy}-4-benzimidazole-phenyl)methoxycarbonylmethylamino]acetic acid methyl ester 6 was synthesized and characterized by single crystal X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), electron spray ionization-mass spectrometry (ESI-HRMS), X-ray powder diffraction (PXRD), 1H and 13C NMR. 6 crystallizes in the centrosymmetric monoclinic space group C2/c, with unit cell parameters a = 35.648(3) Å, b = 14.3240(12) Å, c = 15.3693(13) Å, α= 90.00, β= 94.8190(10), γ = 90.00, V = 7820.16 Å3 and Z = 8 at 296(2) K. As indicated by crystal packing, the molecular conjugation planes arrange along the c axis to form micropores due to the hydrogen bonds. In addition, the fluorescent spectrum and luminescence lifetime were studied for 6.

【 授权许可】

Unknown