期刊论文详细信息
| Journal of the Brazilian Chemical Society | |
| Partial oxidation of methane to syngas on Rh/Al2O3 and Rh/Ce-ZrO2 catalysts | |
| Passos, Fabio B.1 Bitencourt, Isabela G.1 Universidade Federal Fluminense, Niterói, Brazil1 Oliveira, Raquel L.1 | |
| 关键词: methane partial oxidation; methane; ceria-zirconia; rhodium; DRIFTS; | |
| DOI : 10.1590/S0103-50532013000100010 | |
| 学科分类：化学（综合） | |
| 来源: SciELO | |
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【 摘 要 】
The partial oxidation of methane with γ-Al2O3-, CeO2-, ZrO2- and Ce-ZrO2-supported rhodium catalysts was investigated. DRIFTS (diffuse reflectance infrared spectroscopy) measurements of adsorbed CO showed the formation of different rhodium species on different supports, which influenced the dispersion of the metal. The effects of the metal dispersion, oxygen storage capacity on the activity of these catalysts for the partial oxidation of methane are discussed.
【 授权许可】
Unknown
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO201912050581748ZK.pdf | 840KB |  download |
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