Characterization of ZSM-5 modified with niobium pentoxide: the study of thiophene adsorption

Journal of the Brazilian Chemical Society

Universidade de Brasília, Brasília, Brazil¹  Dias, José A.¹  Universidade Federal do Amazonas, Manaus, Brazil¹  Cavalcanti, Rodrigo M.¹  Barros, Ivoneide de C. L.¹  Dias, Sílvia C. L.¹ 

关键词: ZSM-5 zeolite;    niobium pentoxide;    kinetics;    adsorption;    thiophene;   

DOI  :  10.1590/S0103-50532013000100007

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

ZSM-5 adsorbents impregnated with Nb2O5 were applied in the sulfur removal in the form of thiophene, refractory substance of difficult removal of liquid fuels. For this purpose, a model fuel containing iso-octane contaminated with thiophene in concentrations of 877.5 to 1155 ppmw was prepared. The samples were characterized by X-ray diffractometry (XRD), Fourier transform infrared (FTIR) and Fourier transform-Raman (FT-Raman) spectroscopies for confirmation of the adsorbents, being prioritized the adsorption study with that containing 5 wt.% of niobium pentoxide, because it showed a greater capacity for removal of thiophene. The best results of adsorption were achieved at 353 K, a longer time to reach equilibrium was observed. Under these conditions, the best kinetic fitting was achieved using the equation of pseudo-second order, demonstrating the domain of the phenomenon of chemisorption. While under lower temperatures, the diffusion model presented a better approximation of the experimental results. Also, the increasing of temperature did enhance spontaneous processes.

【 授权许可】

Unknown