Dispersive liquid-liquid microextraction procedure for the determination of palladium by flame atomic absorption spectroscopy

Journal of the Brazilian Chemical Society

Saçmacl, Şerife¹  Erciyes University, Kayseri, Turkey¹  Dural, Sevilay¹  Kartal, Şenol¹ 

关键词: palladium;    dispersive liquid-liquid microextraction;    2;    2'-furyldioxime;    atomic absorption spectrometry;   

DOI  :  10.1590/S0103-50532012000600006

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

A new dispersive liquid-liquid microextraction (DLLME) preconcentration method was developed for the determination of palladium. In the proposed approach, 2,2'-furyldioxime was used as chelating agent, while chloroform and methanol were used as extraction and dispersive solvents, respectively. Several factors that influence the microextraction efficiency, such as type and amount of extraction and dispersive solvents, acidity of sample solution, concentration of the chelating agent, and centrifugation time were investigated and the optimized microextraction conditions were established. Under the optimum conditions, the preconcentration factor of this method for palladium was reached at 250. The limit of detection for palladium was 0.04 µg L-1 (3 s), and the relative standard deviation (RSD) was 1.1% (n = 8) at 4 µg L-1 level. The accuracy of the method was performed by analysis of the certified standard reference material (CDN-PGMS-10). The developed method was applied successfully to the determination of palladium in the catalytic converter, anode slime, road sediment and water samples.

【 授权许可】

Unknown