期刊论文详细信息
| Journal of the Brazilian Chemical Society | |
| Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions | |
| Nájera, Carmen1 Universidad de Alicante, Alicante, Spain1 Sansano, José M.1 Yus, Miguel1 | |
| 关键词: asymmetric catalysis; cycloadditions; Lewis acids; organocatalysts; | |
| DOI : 10.1590/S0103-50532010000300002 | |
| 学科分类：化学（综合） | |
| 来源: SciELO | |
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【 摘 要 】
In this review, a comparison between the Lewis acid catalysed and organocatalysed 1,3-dipolar cycloaddition is presented with special focus on the enantioselective synthesis of five-membered hetero- or carbocyclic systems, is described. These reactions exhibit very interesting features, but the most important one is the generation of up to four stereogenic centres in only one reaction step.
【 授权许可】
Unknown
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO201912050580941ZK.pdf | 831KB |  download |
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