SPME-GC-FID method development for analyzing cyclohexanone hydrogenation products

Journal of the Brazilian Chemical Society

Universidade Federal de Minas Gerais, Belo Horizonte, Brazil¹  Cardeal, Zenilda L.¹  Coelho, Adriana R. A.¹  Oliveira, Ione M. F.¹ 

关键词: SPME;    HEC;    cyclohexanone;    chemometrics;   

DOI  :  10.1590/S0103-50532009000300018

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

This work presents a method development for analyzing electrocatalytic hydrogenation products of cyclohexanone with the simple, fast and accurate SPME, coupled with classic gas chromatographic methods using flame ionization detection. Preliminar method optimization was made using chemometric tools. LOD and LOQ obtained were 0.50% conversion or 0.78 mg L-1 and 1.20% conversion or 1.86 mg L-1 respectively. The analytical curve obtained displays good linearity (R2 = 0.9936).

【 授权许可】

Unknown