Electronic nature of the aromatic adamantanediyl ions and its analogues

Journal of the Brazilian Chemical Society

Firme, Caio L.¹  Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brazil¹  Antunes, O. A. C.¹  Esteves, Pierre M.¹ 

关键词: adamantyl dication;    adamantyl cation;    degeneracy;    delocalization index;    ring density;    aromaticity;    tridimensional aromaticity;    1;    3-dehydro-5;    7-adamantanediyl dication;   

DOI  :  10.1590/S0103-50532008000100020

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

The relative stability of the 1,3-dehydro-5,7-adamantanediyl dication is ascribed to its tridimensional aromaticity. However, its electronic nature is not well known. In order to improve its understanding, dicationic and monocationic adamantanedyil species and some

【 授权许可】

Unknown