Synthesis, spectral studies and catalytic activity of ruthenium(II) complexes with organic amide ligands

Journal of the Brazilian Chemical Society

Kakatiya University, Warangal, India¹  Ravinder, Vadde¹  Prasad, Adapa V. S. S.¹  Ashok, More¹ 

关键词: synthesis;    ruthenium complexes;    spectroscopic analysis;    catalysis;    organic amide ligand;   

DOI  :  10.1590/S0103-50532007000800007

学科分类：化学（综合）

来源: SciELO

【 摘 要 】

Twelve new hexacoordinated ruthenium(II) complexes with organic amides, [RuH(CO)(PPh3)2(L2 )], have been synthesized by treating the precursor, [RuH2(CO)(PPh3)3], with twelve different amide proligands separately. These complexes were characterized by elemental analysis and by UV-vis, IR, 1H, 13C and 31P NMR spectroscopies. Molecular formulae and octahedral structures have been tentatively proposed for the products. These complexes were found to be efficient in the catalytic reduction of NO2-containing drugs such as chloramphenicol and metronidazole to their amino derivatives. The percent yields of the reduction products were determined spectrophotometrically.

【 授权许可】

Unknown