期刊论文详细信息
| Journal of the Brazilian Chemical Society | |
| Synthesis of organothioacrylonitriles and organoselenoacrylonitriles by reaction of 1-Halo-1-chalcogenoalkenes with CuCN | |
| Vieira, Adriano S.1 Silveira, Claudio C.1 Mendes, Samuel R.1 Caliari, Vinicius1 Universidade Federal de Santa Maria, Santa Maria, Brazil1 | |
| 关键词: organoselenoacrylonitriles; organothioacrylonitriles; vinylic substitution; cuprous cyanide; vinylic chalcogenides; | |
| DOI : 10.1590/S0103-50532007000800005 | |
| 学科分类：化学（综合） | |
| 来源: SciELO | |
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【 摘 要 】
Reaction of 1-halo-1-organothio or 1-halo-1-organoseleno alkenes with CuCN in NMP as solvent provides a-phenylthio or a-phenylseleno acrylonitriles in good yields. The reaction showed a low stereoselectivity and the products were obtained as E/Z mixtures of isomers.
【 授权许可】
Unknown
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO201912050580299ZK.pdf | 166KB |  download |
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