Mild and Efficient Reagents for Oxidation of Alcohols: [MeOCH2(Ph)3P]+[CrO3X]ֿ, (X=F, Cl)

The Journal of Pure and Applied Chemistry Research

Amir Lashgari¹  Shahriar Ghamami¹ 

[1] Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin,, Iran$$

关键词: desulfurization;    benzothiophene;    keggin;    polyoxometalate;   

DOI  :  10.21776/ub.jpacr.2015.004.01.190

来源: University of Brawijaya

【 摘 要 】

Two fast, mild, and reasonable oxidizing agents, Methoxymethyltriphenylphosphonium Halochromates (VI), [MeOCH 2 (Ph) 3 P] + [CrO 3 X]ֿ (MMTriPPXC) are synthesized. The preparations of Methoxymethyltriphenylphosphonium Halochromates are new and efficient reagents for the oxidation of primary and secondary alcohols to their corresponding carbonyl compounds in dichloromethane at ambient temperature. These are obtained with relatively short reaction times.  The oxidants/substrates ratios of 1:1 are employed.

【 授权许可】

Unknown