Molecularly imprinted polymers: a new approach to the preparation of functional materials

Proceedings of the Estonian Academy of Sciences

Andres Öpik¹  Vitali Syritski¹  Anna Menaker¹  Jekaterina Reut¹ 

[1] $$

关键词: polymer materials;    electrically conducting polymers;    molecular imprinting;    enantioselective recognition;    surface imprinting;    proteins;   

DOI  :  10.3176/proc.2009.1.01

学科分类：化学（综合）

来源: Teaduste Akadeemia Kirjastus

【 摘 要 】

Molecular imprinting is a method for creating specific cavities in synthetic polymer matrices with memory for the template molecules. To date molecularly imprinted polymers (MIPs) have obtained a strong position in materials science and technology, expanding significantly the list of functional materials. This article provides a short review of the molecular imprinting technique with special attention paid to electrosynthesized electrically conducting polymers (ECPs), polypyrrole and poly­ethylenedioxythiophene, as matrix materials for molecular imprinting. We describe two different ECP-based MIP systems: enantioselective thin films of overoxidized polypyrrole imprinted with L-aspartic acid and surface imprinted polyethylene­dioxythiophene for selective protein adsorption.

【 授权许可】

Unknown