Base-oxidant promoted metal-free N-demethylation of arylamines

Journal of Chemical Sciences

CHIRANJEEVI BARREDDI¹  VINAYAK BOTLA¹  RAMANA V DAGGUPATI¹  CHANDRASEKHARAM MALAPAKA¹ 

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关键词: N;    N-dialkylaniline;    N-dealkylation;    Triethylamine;    tert-butyl hydroperoxide;    metal-free.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

A metal-free oxidative N-demethylation of arylamines with triethylamine as a base and tert-butyl hydroperoxide (TBHP) as oxidant is reported in this paper. The reaction is general, practical, inexpensive, non-toxic, and the method followed is environmentally benign, with moderate to good yields.

【 授权许可】

Unknown