Synthesis, crystal structure and Thermogravimetry of ortho-phthalic acid bridged coordination polymer of Copper(II)

Journal of Chemical Sciences

DIGANTA KUMAR DAS¹  SAURAV BHARALI¹  BABITA SARMA¹ 

[1] $$

关键词: o-Phthalic acid;    Coordination polymer;    X-ray Crystal structure;    Copper(II);    EPR;    TGA.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

Coordination polymer of Cu(II) bridged by o-phthalic acid alone is not known. The reaction of$CuCl_{2}.2H_{2}O$ with (2-butoxycarbonyl)benzoic acid yielded three dimensional coordination polymer bridged byo-phthalic acid. X-ray crystal structure shows structure with monoclinic P21/c space group. o-Phthalic acidmolecules act as bridge between two Cu(II), one carboxylate binds to one Cu(II) as bidentate while the othercarboxylate binds to another Cu(II) as monodentate. The four planar co-ordination positions of Cu(II) aresatisfied by two chelated carboxylates while fifth and sixth co-ordination positions are satisfied by monodentatecarboxylates. EPR and TGA of the coordination polymer are also reported.

【 授权许可】

Unknown