Ionothermal synthesis and structural characterization of [Cu(C4H6N2)4]Br2 and [Ni(C4H6N2)4]Br2

Journal of Chemical Sciences

Qinghai Cai2²  Jingxiang Zhao²  Bin Lu²  Hong Wang¹ 

[1] School of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150080, P. R. China$$;School of Chemistry and Chemical Engineering, Harbin Normal University, No. 1 Shida Road Limin development Zone, Harbin 150025, P. R. China$$

关键词: Ionothermal technique;    ionic liquid;    single crystal;    crystal structure.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

The ionothermal synthesis and spectroscopic, thermal and structural characterization of two new compounds [Cu(C4H6N2)4]Br2 (1) and [Ni(C4H6N2)4]Br2 (2) [(C4H6N2) = N-methylimidazole] are reported. In both 1 and 2, the central metal Cu (or Ni) ion adopts a square planar geometry and is bonded to the N-atoms of four terminal N-methylimidazole ligands.

【 授权许可】

Unknown