Synthesis, characterization and DFT studies of 1, 1′-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes

Journal of Chemical Sciences

Raghavan B Sunoj²  Sandeep Kaur-Ghumaan1¹  A Sreenithya² 

[1] Department of Chemistry, University of Delhi, Delhi 110007, India$$;Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India$$

关键词: Bioinorganic chemistry;    hydrogenase enzyme;    bidentate phosphine;    proton reduction;    redox active ligands;    density functional calculations.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

The reaction of [Fe2(CO)6(𝜇-toluene-3, 4-benzenedithiolate)] 1 and bidentate diphosphine, 1, 1′-bis(diphenylphosphino)ferrocene (dppf) has been studied. New complexes obtained have been characterized by various spectroscopic techniques as bioinspired models of the iron hydrogenase active site. The crystal structure of [Fe2(CO)5(𝜅1-dppfO)(𝜇-toluene-3, 4-benzenedithiolate)] 4 is reported.

【 授权许可】

Unknown