Synthesis and crystal structure of a wheel-shaped supramolecular coordination complex

Journal of Chemical Sciences

Firasat Hussain¹  Palanisamy Rajakannu¹  Malaichamy Sathiyendiran1¹  Bhaskaran Shankar¹  Deepak Gupta¹ 

[1] Department of Chemistry, University of Delhi, Delhi 110 007, India$$

关键词: Rhenium;    molecular ring;    anthraquinone;    non-covalent interactions;    supramolecules;    X-ray structure.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

Supramolecular coordination complex (SCC) possessing spatially arranged three anthraquinone dimers in a slipped-cofacial orientation was achieved by the treatment of Re2(CO)10, 2-hydroxymethylanthraquinone and tritopic N-donor via fac-Re(CO)3-directed one pot approach. The off-set 𝜋-stacking and C≡O…H bonding interactions stabilize the ring structure.

【 授权许可】

Unknown