Assembling of H5PW10V2O40/MCM-48 and studying its superior catalytic performance in the synthesis of 14-aryl-14-H-dibenzo[a, j]xanthenes

Journal of Chemical Sciences

Behrouz Maleki¹  Reza Tayebee1¹ 

[1] Department of Chemistry, School of Sciences, Hakim Sabzevari University, Sabzevar 96179-76487, Iran$$

关键词: Xanthene;    heteropolyacid;    keggin;    solvent-free;    heterogeneous;    MCM-48.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

A highly efficient, green, and reusable heterogeneous catalytic system is introduced for the preparation of aryl-14-H-dibenzo[a,j]xanthenes via one-pot condensation of 𝛽-naphthol with aryl-aldehydes by the mediation of a heterogeneous material composed of Keggin%-type tungsto-divanado-phosphoric acid, H5PW10V2O40, supported on MCM-48 under solvent-free condition. Excellent yields (85-100%), short reaction time (<60 min.), mild condition, simple work-up, and using a cheap and environmentally friendly catalyst bearing remarkable reusability are advantages of the present methodology. The catalytic efficacy of H5PW10V2O40/MCM-48 over some reported protocols are also overviewed.

【 授权许可】

Unknown