Sheet-like of MoV-SmIII assembly containing [MoV(CN)8]3- and Sm3+ ions as building blocks

Journal of Chemical Sciences

Dai-Zheng Liao2¹  Yue Ma¹  Shu-Lin Ma1²  Shi Ren² 

[1] Department of Chemistry, Nankai University, Tianjin, 300071, PR China$$;Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134, PR China$$

关键词: Cyano bridges;    ferromagnetic coupling;    𝜋-𝜋 stacks;    3D network structure.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

The reaction of [Mo(CN)8]3- with Sm3+ and 2,2'-bipyridine (bpy) lead to a sheet-like bimetallic complex, {Sm(H2O)9[Sm2(bpy)2(OH)2.75(NO3)0.25][Mo(CN)8]2}𝑛 (1) in EtOH/H2O mixture solvent. The complex 1 crystallizes in monoclinic, space group 𝐶2/𝑐. The structural investigation denotes that the layers interaction with each other by 𝜋-𝜋 stacks and hydrogen bonds result in a 3D network, containing Sm(H2O)$^{3+}_{9}$ as guest molecules in the holes. The magnetic behaviour of the complex 1 has been studied.

【 授权许可】

Unknown