期刊论文详细信息
Journal of Chemical Sciences | |
Gold(III)pentafluorophenylarylazoimidazole: Synthesis and spectral (H, C, COSY, HMQC NMR) characterisation | |
Prithwiraj Byabartta11  Mariano Laguna1  | |
[1] Departmento de Quimica Inorganica-Instituto de Ciencia deMateriales de Aragon, Universidad de Zaragoza-CSIC, Zaragoza-50009, Spain$$ | |
关键词: Gold(I); 1-alkyl-2-(arylazo)imidazole; 1H; 13C; 19F; COSY; HMQC NMR.; | |
DOI : | |
来源: Indian Academy of Sciences | |
【 摘 要 】
Reaction of [AuIII(C6F5)3(tht)] with RaaiR' in dichloromethane medium leads to [AuIII(C6F5)3 (RaaiR')] [RaaiR' = ð‘-R-C6H4-N=N-C3H2-NN-1-R', (1-3), R = H (a), Me (b), Cl (c) and R' = Me (1), CH2CH3 (2), CH2Ph (3), tht is tetrahydrothiophen]. The nine new complexes are characterised by ES/MS as well as FAB, IR and multinuclear NMR (1H, 13C, 19F) spectroscopic studies. In addition to dimensional NMR studies as 1H, 1H COSY and 1H 13C HMQC permit complete assignment of the complexes in the solution phase.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912040507792ZK.pdf | 125KB | download |