Hydrothermal syntheses and single crystal structural characterization of M(H2O)6(OPTA)2 [M = Co(II), Ni(II), Zn(II); OPTA = 1-oxopyridinium-2-thioacetato]

Journal of Chemical Sciences

A McAneny²  P Ramadevi³  R D Walsh¹  S Kumaresan1³  C H Lake² 

[1] Department of Chemistry, University of South Florida, SCA 400, 4202, East Fowler Avenue, Tampa, FL 33620-5250, USA$$;Department of Chemistry, Indiana University of Pennsylvania, Indiana, PA 15701, USA$$;Department of Chemistry, Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli 627 012$$

关键词: Hydrothermal;    ionic crystals;    cobalt;    nickel;    zinc;    1-oxopyridinium-2-thioacetato.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

A new class of compounds of the family M(H2O)6(OPTA)2 (where M = Co(II), Ni(II), and Zn(II); OPTA = 1-oxopyridinium-2-thioacetato) was prepared from the appropriate metal acetates, 1-oxopyridinium-2-thioacetic acid (OPTAH), and potassium hydroxide in hydrothermal media and structurally characterized. The structure is constructed from M(H2O)$_{6}^{2+}$ and two anions of OPTAH (C7H6NO3S) linked through hydrogen bonding into an extended network.

【 授权许可】

Unknown