Core-modified octaphyrins: Syntheses and anion-binding properties

Journal of Chemical Sciences

Tavarekere K Chandrashekar1 2²  Venkataramanarao G Anand¹  Rajneesh Misra²  Harapriya Rath² 

[1] Present address: Regional Research Laboratory, Trivandrum 695 019, India$$;Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India$$

关键词: Anion binding;    aromaticity;    34𝜋 electrons;    octaphyrin;    oxidative coupling reactions.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

In this paper, a brief review of the syntheses, characterization and anion-binding properties of core-modified octaphyrins is presented. It has been shown that the core-modified octaphyrins exhibit aromaticity both in solution and in solid state, confirming the validity of the (4𝑛 + 2) Huckel rule for larger 𝜋-electron systems. Solid-state binding characteristics of TFA anions of two core-modified octaphyrins are also described.

【 授权许可】

Unknown