Epoxidation and oxidation reactions using 1,4-butanediol dimethacrylate crosslinked polystyrene-supported tertiary butyl hydroperoxide

Journal of Chemical Sciences

K Sreekumar2²  M S Sheela¹ 

[1] Department of Chemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram 695 581, India$$;Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682 022, India$$

关键词: Polystyrene-supported reagent;    t-butyl hydroperoxide;    solid-phase organic reagent;    recyclability;    epoxidation;    oxidation.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

1,4-Butanediol dimethacrylate (1,4-BDDMA) crosslinked polystyrene-supported 𝑡-butyl hydroperoxide was employed in the epoxidation of olefins and oxidation of alcohols to carbonyl compounds. The reagent proved to be successful as a recyclable solid phase organic reagent with as much or more efficiency when compared to its monomeric counterpart. The extent of reaction was found to be dependent on various reaction parameters like solvent, temperature, molar concentration and presence of catalyst.

【 授权许可】

Unknown