期刊论文详细信息
Journal of Chemical Sciences | |
Catalytic effects of poly(methyl methacrylate)-supported ð›½-diketone-linked palladium complexes in olefin oxidation | |
M M Suni1  Vipin A Nair11  K Sreekumar2  | |
[1] Department of Pharmaceutical Sciences, University of Tennessee, 847 Monroe Avenue, RM 327, Memphis, TN 38163, USA$$;Department of Applied Chemistry, Cochin University of Science and Technology, Cochin 682 022, India$$ | |
关键词: Palladium complexes; poly(methyl methacrylate) support; olefin oxidation; ð›½-diketone-linked complexes.; | |
DOI : | |
来源: Indian Academy of Sciences | |
【 摘 要 】
Poly(methyl methacrylate)-supported ð›½-diketone-linked palladium complexes on refluxing with olefins at 70°C in methanol-water medium for 10 h afforded carbonyl compounds. The course of the reaction was found to be influenced by the degree of cross-linking of the polymer matrix and the structural environment of the ligand. The reaction is assumed to proceed through a hydroxy palladation intermediate. A suitable mechanism is also suggested.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912040507494ZK.pdf | 44KB | download |