期刊论文详细信息
Journal of Chemical Sciences | |
Intervalence charge transfer transition in mixed valence complexes synthesised from RuIII(edta)- and FeII(CN)5-cores | |
Atindra D Shukla1  Amitava Das11  H C Bajaj1  | |
[1] Central Salt and Marine Chemicals Research Institute, Bhavnagar 364 002, India$$ | |
关键词: Mixed valence complexes; intervalence charge transfer; rotaxane; inclusion complex; optical electron transfer; cyclodextrin.; | |
DOI : | |
来源: Indian Academy of Sciences | |
【 摘 要 】
Intervalence charge transfer properties were studied for a set of mixed valence complexes incorporating Ru(III) and Fe(II)-centres linked by various saturated and unsaturated bridging ligands (BL). Studies reveal that degree of ground state electronic interaction and coupling between Ru(III) and Fe(II)-centres can be attenuated by changing the nature of the bridging ligand. Further, inclusion of the bridging ligand with interrupted ðœ™-electron system in a ð›½-CD cavity initiate an optical electron transfer from Fe(II) to Ru(III) which is otherwise not observed.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912040507489ZK.pdf | 134KB | download |