Copper(II) complexes with aroylhydrazones

Journal of Chemical Sciences

Samudranil Pal1¹ 

[1] School of Chemistry, University of Hyderabad, Hyderabad 500 046, India$$

关键词: Copper(II) complexes;    aroylhydrazones;    crystal structures;    intermolecular interactions;    self-assembly;    magnetic properties;    imine to imidate transformation.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

The coordination chemistry of copper(II) with tridentate aroylhydrazones is briefly discussed in this article. Two types of aroylhydrazones derived from aroylhydrazines and ortho-hydroxy aldehydes or 2-pyridine-carboxaldehyde have been used. The characterization of the complexes has been performed with the help of various physico-chemical techniques. Solid state structural patterns have been established by X-ray crystallography. In the solid state, structural varieties of these complexes are seen to range from monomeric, dimeric, polymeric and onedimensional self-assembly via hydrogen bonds and 𝜋-𝜋 interactions. EPR spectroscopy and variable temperature magnetic susceptibility measurements have been used to reveal the nature of the coordination geometry and magnetic characteristics of these complexes.

【 授权许可】

Unknown