Si-O and P-O motifs in inorganic rings and clusters

Journal of Chemical Sciences

S Nagendran¹  V Chandrasekhar1¹  V Krishnan¹  S Kingsley¹  R Boomishankar¹ 

[1] Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India$$

关键词: Silanols;    metallasiloxanes;    hydrogen bonding;    phosphonates;    metal clusters.;   

DOI  :  

来源: Indian Academy of Sciences

【 摘 要 】

This article presents a brief overview of different kinds of silanols and the important reactions of N-bonded silanetriols. The synthesis and characterization of silanediols containing Si-N and Si-C bonds, (2,4,6-Me3C6H2)N(SiMe3)Si(Me)(OH)2 (1e) is described. 1e shows a polymeric crinkled tape type of structure due to extensive intermolecular hydrogen bonding. We also describe the formation of a neutral copper(II) complex derived from the reaction of CuCl2 with (O)P(3,5-Me2Pz)3 where the ligand undergoes a facile P-N bond cleavage and functions as an N2O type of tridentate ligand.

【 授权许可】

Unknown