A phase-matchable nonlinear optical crystal 4-amino-5-mercapto-3-[1-(4-isobutylphenyl)ethyl]- 1,2,4-triazole: Synthesis, crystal growth and characterization

Pramana

K V Sujith²  Balakrishna Kalluraya²  K Naseema¹  Vijayalakshmi Rao1¹ 

[1] Department of Materials Science, Mangalore University, Mangalagangothri 574 199, India$$;Department of Chemistry, Mangalore University, Mangalagangothri 574 199, India$$

关键词: Non-linear optical crystal;    growth from solution;    characterization;    organic material.;   

DOI  :  

学科分类：物理（综合）

来源: Indian Academy of Sciences

【 摘 要 】

In this paper, we report the synthesis, growth and characterization of a new organic NLO single crystal of 4-amino-5-mercapto-3-[1-(4-isobutylphenyl)ethyl]-1,2,4-triazole (AMIT). The title compound is synthesized and single crystals were grown by the slow evaporation technique at room temperature. The grown crystal was characterized by powder XRD, FTIR, UV–Vis. and microhardness studies. The thermal analysis of the crystal was carried out by TGA, DTA and DSC. From DSC, the melting point of the crystal is found to be 168°C. The scanning electron microscopy (SEM) provides information about the surface morphology of the crystal. The SHG efficiency has been estimated as 0.3 times that of KDP using Kurtz powder method and is found to be a phase-matchable NLO crystal.

【 授权许可】

Unknown