Theoretical approach to the magnetic properties of Mn(II), Cr(III), and Cu(II) complexes in the newly reported 12- and 15-membered macrocyclic ligands

Pramana

Mustafa Karkaplan¹  Ali Bayri1² 

[1] Chemistry Department, Science and Arts Faculty, Inonu University, Malatya, Turkey$$;Physics Department, Sciences and Arts Faculty, Adiyaman University, Adiyaman, Turkey$$

关键词: Magnetization;    magnetic susceptibility;    spin-orbit coupling;    zero-field splitting;    macrocyclic complexes;    covalancy factor.;   

DOI  :  

学科分类：物理（综合）

来源: Indian Academy of Sciences

【 摘 要 】

The magnetic properties of Cu2+, Cr3+, and Mn2+ ions in the newly reported 12- and 15-membered macrocyclic complexes are analysed by a theoretical approach. The calculated magnetic moment and magnetic anisotropy for various situations, especially for Cu(II) ion, suggest that the magnetic properties may lead to a better interpretation about the geometry. It is also suggested that the zero-field splitting Hamiltonian may be used for magnetic properties of some metal ions, which have orbital singlet ground term in these complexes.

【 授权许可】

Unknown